Two-dimensional heterodyne-detected vibrational sum-frequency generation (2D-HD-VSFG) spectroscopy of water at interfaces has been realized for the first time. In the present study. 2D-HD-VSFG spectra were measured at a charged monolayer / isotopically diluted water interface. In contrast to the 2D-IR spectrum of bulk isotopically diluted water. https://sportshutes.shop/product-category/drinkware/